Identity

Formula CaF2
Class Halides
Crystal System Cubic
Hardness 4
Color Purple, green, blue, yellow, colorless, pink, brown; often banded
Lustre Vitreous
Specific Gravity 3.18
Cleavage Perfect octahedral, four directions
Streak White
Technical notes (click to open)(click to close)
Species established 1797, by Carlo Antonio Galeani Napione
Refractive index 1.434, isotropic, unusually low for a mineral
Dispersion 0.007, very low, the reason it makes excellent apochromatic lenses
Specific gravity 3.18
Twinning Interpenetration twins of two cubes on {111}, very common and diagnostic
Cause of color No single element. Color centers from natural radiation, plus rare earth elements such as yttrium and cerium, and other trace impurities
Cause of fluorescence Usually traces of rare earth elements. The classic blue-white glow comes from divalent europium
Named varieties Blue John (banded purple and white), chlorophane (glows when gently warmed), antozonite (dark fetid fluorite that releases a sharp smell when crushed)
Telling it apart Softer than quartz (4 versus 7) and shows cleavage that quartz lacks. Lighter than barite. The cube-and-octahedron habit plus octahedral cleavage usually confirm it

Name & Human History

Etymology

Fluorite gets its name from the Latin word fluere, which means to flow. The reason is its oldest job. When you add fluorite to a hot furnace, it lowers the melting point of metal ores and helps the liquid metal flow more easily. Workers long ago called minerals like this fluores. The stone also gave its name to two famous things in science. One is the element fluorine, which was first taken from fluorite. The other is fluorescence, the glow that some materials give off under special light, first studied in fluorite.

Through the Ages

For most of its history, fluorite was used for work, not for beauty. It was mostly a helper in the furnace, just as its name says. One famous exception is a banded purple and yellow kind called Blue John, found in Derbyshire, England. Since the 1700s, people have carved Blue John into bowls, vases, and ornaments. The Romans may have prized a similar banded fluorite for costly cups, though experts still argue about that.

Today

Today, fluorite is the main source of the element fluorine. Most mined fluorite is turned into an acid that is the starting point for many products. These include the coolant in refrigerators, tough plastics, and many medicines. Fluorite also still helps melt metal in steel and aluminum plants. The clearest, purest crystals have a special use. They bend light very evenly, with almost no color spread, so they are cut into lenses for microscopes, telescopes, and fine cameras.

Geology & Occurrence

Formation

Fluorite usually grows from hot, mineral-rich water moving through cracks in the rock. As the water cools, fluorite lines the cracks. It often grows next to minerals like galena, sphalerite, barite, quartz, and calcite. It can also form in other settings, such as where these fluids react with limestone. One of its most famous traits is the way it breaks. A cube of fluorite can split cleanly into a perfect eight-sided shape, which makes it a favorite for teaching about crystals.

Notable Localities

England set the standard, with deep purple and green crystals from County Durham and Derbyshire. Spain produces clear yellow and violet crystals. China mines more fluorite than any other country. In the United States, southern Illinois was a major source, and fluorite is the state mineral there. Fine specimens also come from Mexico and Morocco.

Did you know?

Fluorite is the stone that gave a whole effect its name. In 1852, a scientist named George Stokes was studying how some materials glow under invisible ultraviolet light. The fluorite he used did this so well that he named the effect after it: fluorescence. Today that word covers everything from highlighter ink to glowing safety vests, all traced back to a glowing violet crystal.

Fluorite is a chameleon of color. The same mineral can be purple, green, blue, yellow, pink, or clear. A single crystal often stacks several of these colors in sharp bands. Some pieces even glow one color in daylight and a different color under ultraviolet light.

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